LEVELS OF HEAVY METALS CONCENTRATIONS IN CHOCOLATES FROM BWARI MARKET ABUJA FCT, NIGERIA

Authors

  • Daniel Agbaghare Veritas University Abuja
  • Emmanuel, Joy Enogbe Veritas University Abuja

Keywords:

Chocolate, Concentrations, Spectrometry, Acid digestion, heavy metals

Abstract

The concentration of some heavy metals in chocolates consumed in Bwari Area Council Abuja F.C.T, Nigeria were determined and the metal concentrations were compared with regulatory standards. Two brands of chocolate were purchased from Bwari market. The concentrations of Ni, Fe, Cu, Cr, and Pb were determined using Atomic Absorption Spectrophotometry (AAS). The mean concentrations of Ni, Fe, Cu, Cr, and Pb were found to be 0.98 + 0.05, 6.48 + 0.37, 5.01 + 0.03, 4.08+ 0.41, and 0.24 + 0.12 mg/kg respectively and were compared to world health organisation standard (WHO). Estimated daily intake for each metal in the respective samples were also determined, showing that the trends of daily intake of heavy metals in the samples were in the order: Fe>Cu>Cr>Ni>Pb. The findings of the study indicates that the concentrations of the studied brands of chocolate from Bwari market are within the allowable limits hence pose no potential health risk or hazard upon consumption.

Author Biography

Emmanuel, Joy Enogbe, Veritas University Abuja

Department of Pure and Applied Chemistry

References

Mohammed, A. I., Ahmed, A. A., Lot, T. & Solomon, M. Assessment of some heavy metals in some chocolate brands and bread sold in Maiduguri, Borno state, Nigeria. Chemistry & Material Sciences Research Journal. (2020); 2(4): 71-75,

Arévalo-Gardini E, Arévalo-Hernández CO, Baligar VC, He ZL. Heavy metal accumulation in leaves and beans of cacao (Theobroma cacao L.) in major cacao growing regions in Peru. Science of the Total Environment. 2017 Dec 15;605:792-800.

Garba I, Mustapha M. Assessment of some heavy metals contamination in some brands of chocolates and chewing gum available in Kano Metropolitan. International Journal of Recent Research in Physics and Chemical Sciences. 2018;5(1):10-7.

Agbaghare, D. E. & Agbaghare, G. O. (2024). Kinetic analysis of the sorption removal of copper (ii) from aqueous solution by plantain peel 7(2), 1-7 https://www.researchgate.net/publication/384837979

Kazi, R. P., Tanvir A. C., Tanvir, R., Sharmin, Z. E., Abrar, H., Hredoy, G. R., & Abdurrahim. M. Microbiological analysis and content of heavy metals in different candies, chocolates, and their wrappers in Banglades. International Journal of Food Science. (2024). 1-13

Dauda, J. A., Ameha, E. M., Usmana, O. S. et al. Determination of heavy metals in different brand of chocolates, marketed in Anyigba, Kogi State. NIPES Journal of Science and Technology Research. (2021); 3(3): 22 - 27

World Health Organization (WHO) (2001). Environmental Health Criteria 224: Guidelines for the study of dietary intakes of chemical contaminants. World Health Organization, Geneva.

AOAC. (1998). Official Methods of Analysis of AOAC International, 16th Edition, 4th Revision. Washington D.C. U.S.A. Pp 70-90.

Godebo TR, Stoner H, Kodsup P, Bases B, Marzoni S, Weil J, Frey M, Daley P, Earnhart A, Ellias G, Friedman T. Occurrence of heavy metals coupled with elevated levels of essential elements in chocolates: Health risk assessment. Food Research International. 2024 Jul 1;187:114360.

Arévalo-Gardini E, Arévalo-Hernández CO, Baligar VC, He ZL. Heavy metal accumulation in leaves and beans of cacao (Theobroma cacao L.) in major cacao growing regions in Peru. Science of the Total Environment. 2017 Dec 15;605:792-800.

FAO/WHO (2011). Codex general standard for contaminants and toxins in food and feed. Available in http://www.codexalimentarius.net/download/standards/17/cxs_193e.pdf.

Salama, A. K. & Radwan, R. M. (2005). Heavy metals (Cd, Pb) and trace elements (Cu, Zn) contents in some foodstuffs from the Egyptian market. Emirate Journal of Agricultural Science. 17(1): 34–42.

Sager, M. (2012). Chocolate and cocoa products as a source of essential elements in nutrition. Journal of Nutrition and Food Sciences. 2(1): 1-10.

Iwegbue, C. M. (2011). Concentration of selected metals in candies and chocolates consumed in southern Nigeria. Food additives and Contaminants, Part B 4(1): 22 – 27

AOAC. (1998). Official Methods of Analysis of AOAC International, 16th Edition, 4th Revision. Washington D.C. U.S.A. Pp 70-90.

USEPA (1989). Evaluation of the potential carcinogenicity of lead and lead compounds. Office of Health and Environmental Assessment. EPA/600/8-89/045A

Published

2025-06-30